A universal driver

 

Cassini's Grand Finale never ceases to amaze, this time with Titan and precursors to life totally unexpected in a place as cold and remote as Saturn's largest moon.

The international Cassini-Huygens mission has made a surprising detection of a molecule that is instrumental in the production of complex organics within the hazy atmosphere of Saturn’s moon Titan.

Titan boasts a thick nitrogen and methane atmosphere with some of the most complex chemistry seen in the Solar System. It is even thought to mimic the atmosphere of early Earth, before the build-up of oxygen. As such, Titan can be seen as a planet-scale laboratory that can be studied to understand the chemical reactions that may have led to life on Earth, and that could be occurring on planets around other stars.

These large molecules drift down towards the lower atmosphere, forming a thick haze of organic aerosols, and are thought to eventually reach the surface. But the process by which simple molecules in the upper atmosphere are transformed into the complex organic haze at lower altitudes is complicated and difficult to determine.

One surprising outcome of the Cassini mission was the discovery of a particular type of negatively charged molecule at Titan. Negatively charged species – or ‘anions’ – were not something scientists expected to find, because they are highly reactive and should not last long in Titan’s atmosphere before combining with other materials. Their detection is completely reshaping current understanding of the hazy moon’s atmosphere.

In a new study published in Astrophysical Journal Letters, scientists identified some of the negatively charged species as what are known as ‘carbon chain anions’. These linear molecules are understood to be building blocks towards more complex molecules, and may have acted as the basis for the earliest forms of life on Earth. 

Chemistry in Titan's atmosphere

Addendum: Another Titan surprise, this time regarding cellular membranes.

"The ability to form a stable membrane to separate the internal environment from the external one is important because it provides a means to contain chemicals long enough to allow them to interact," said Michael Mumma, director of the Goddard Center for Astrobiology, which is funded by the NASA Astrobiology Institute. "If membrane-like structures could be formed by vinyl cyanide, it would be an important step on the pathway to life on Saturn's moon Titan."

NASA scientists have definitively detected the chemical acrylonitrile in the atmosphere of Saturn's moon Titan, a place that has long intrigued scientists investigating the chemical precursors of life. On Earth, acrylonitrile, also known as vinyl cyanide, is useful in the manufacture of plastics. Under the harsh conditions of Saturn's largest moon, this chemical is thought to be capable of forming stable, flexible structures similar to cell membranes.

Nature finds a way, always.